Naphthalene, acenaphthene and luorene are wellknown organic chemicals that are useful as intermediates in the production of organic acids, dyes and insecticides. Previously acenaphthene and iluorene have been recovered from coal tar distillates or prepared by synthetic methods.
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A kind of method for preparing naphthalene at first is a Doak Tar Oil, and the boiling range of further purifying is 205～235 ℃ a coal tar distillate that obtains like this is commonly referred to naphtalene contain the such heterocycle component of naphthalene, methylnaphthalene, phenolic compound and benzothiophene, (G, people such as Gilbert, Ind, Eng, Chem, 53 ...
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To develop the in situ underground pyrolysis process of tarrich coal more scientifically, the effect of temperature and pressure on the distribution of pyrolysis products should be clarified. This paper selected the typical components in five distillates of light tar, phenol tar, naphthalene tar, washing tar, and anthracene tar as the main reaction products. 32 typical secondary reactions ...
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Naphthalene production and uses 299 Naphthalene recovery Coal tar is the traditional feedstock for the recovery of naphthalene. The introduc tion of new cracking processes in the last decades has given rise to the availability of petroleumbased raw materials. In addition to coalderived naphthalene, petro
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These advantages of the hydrorefining process have attracted the attention of numerous investigators. A laboratory study has been made of the effects of temperature, partial hydrogen pressure, and space velocity on the amounts of thionapthen and tetralin in the hydroraffinate made by the catalytic hydrorefining of coaltar naphthalene.
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Coal Tar and its Distillation Processes. Coal tar, also known as crude tar, is the byproduct generated during the high temperature carbonizing of coking coal for the production of the metallurgical coke in the byproduct coke ovens. It is a black, viscous, sometimes semisolid, fluid of peculiar smell, which is condensed together with aqueous ...
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To trace the behavior of naphthalene in the pyrolysis of coal tar, the pyrolysis of coal tar containing 14Clabeled naphthalene was carried out at 800−950 °C for 40−50 s. It was found that naphthalene has significant pyrolysis reactivity. The distributions of the radioactivities in compounds with 3−5 rings were,, and % at 800, 900, and 950 °C for 50 s, respectively ...
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Coal tar is a byproduct of coal that is released from various processes of the coal gas and coking process. It is semiliquid in nature with a density of to g/cm 3 and has a foul smell [].. Polycyclic aromatic hydrocarbons (PAHs) are a group of organic compounds that are lifethreatening because of their chemical structures, that consist of benzene rings bonded in a linear and ...
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The coal tar evaluation process of its constituent components is carried out by distillation, with a high level of naphthalene purity achieved up to 96%. The coal tar distillation process normally ...
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Introduction. The carbonization of coal to produce metallurgical coke in slottype recovery ovens is the main source of coal tar production, with this coal conversion process constituting the second largest application of coal. Coal tar production is not a primary process target: the main target in the process is the production of metallurgical ...
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naphthalene oil. NPCs. normalphase columns. OBSG. octyl bonded silica gel. OCAs. ... while the latter is a byproduct from coal coking process [1]. The output of coal tar accounts for 35% of coals in the furnace [2]. ... Li YC, Xin WL, Huang MG, et al. Industrial production technology of coal series needle coke. CN A, ...
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Naphthalene is the most simple, commonly found, and most watersoluble PAHs in the environment. It is produced from coal tar fraction by crystallization and distillation. It is often used as dispersants in natural and synthetic rubbers, in the production of naphthalene sulfonate superplasticizers for concrete, in paints, tanning agents in the leather industry, in the production of the ...
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Coal tar is an important raw material for the production of valuable aromatic compounds [].It has more than 500 components, most of which are aromatic hydrocarbons, including benzene, toluene, xylene, anthracene, naphthalene, and phenanthrene [4, 5].These are precursors for the synthesis of products such as dyes, drugs, explosives, scents, preservatives, synthetic tars, paints, and pigments.
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Abstract In this study, the steam reforming of naphthalene and pyrene as heavy tar model compounds was investigated experimentally in a horizontal tube reactor and theoretically using the CHEMKIN simulation. The experimental results revealed that the reactivity of naphthalene was higher than that of pyrene in the presence of steam. The carbon content converted to soot is a little more than ...
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Coal tar naphthalene oil fraction (CTNOF) is typically obtained as a byproduct of the coking process in steel production. When coal is subjected to high temperatures in the absence of air (coking), it undergoes thermal decomposition, yielding various byproducts including coal tar [].This tar can be further processed to extract different fractions, one of which is naphthalene oil [2, 3].
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Naphthalene Production from coal tar; The distillation and fractionation techniques are used in this process. Crude naphthalene is produced by cooling and crystallizing the middle portions, which contain the majority of the naphthalene. In order to produce refined naphthalene, the crude product is then placed into a distillation, washing, and ...
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The study describes the effect of silicon carbide (SiC) nanopowder on the process of coal tar pitch thermal decomposition during heat treatment to a temperature of 2000 ° influence of nanosized SiC powder on the pyrolysis mechanism of carbonisation product yield, as well as structural and microstructural parameters of carbon obtained via carbonisation and further heating up to 2000 °C ...
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But because that its relative density is higher than and asphaltene content is close to 50% [6] (mass fraction), hightemperature coal tar is not suitable for the production of aerospace fuel. Medium and low temperature coal tar is a liquid product with high condensation degree obtained by pyrolysis of lowrank coal at 600 to 800°C.
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Naphthalene is obtained from either coal tar or petroleum distillation and is primarily used to manufacture phthalic anhydride. Let us see how naphthalene is obtained from coal tar. Step 1: coal tar is the raw material used. Step 2: Naphthalene is fractionated through a weight removing column. Step 3: crude naphthalene is obtained and then ...
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article{osti_, title = {Process and apparatus for the separation of crude benzol and naphthalene from washing oil}, author = {Ullrich, H}, abstractNote = {A process and apparatus for the regeneration of washing oil which has been spent to recover naphthalene and/or benzol from coke oven gas. The spent washing oil is stripped by steam in a bubble column arranged as an integral part of a ...
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Crystallization has advantages for the production of highly purified products, such as operation at low temperatures compared to vaporliquid processes, ... Purification of naphthalene from naphthalenerich oil of coal tar distillates was explored by using the melt and solution crystallizations. The solidliquid equilibrium of naphthalene ...
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But nowadays Bitumen has replaced coal tar to serve this purpose. Naphthalene balls used as moth repellent in the storage areas are the derivatives of coal tar. ... The production process is distinct, both physically and chemically, from that used to create a range of gaseous fuels known variously as manufactured gas, syngas, hygas, Dowson gas ...
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1. Introduction. With the development of coal utilization technologies such as gasification, liquefaction, carbonization, and coking, a large number of coal tar or coal tar byproducts have been produced, among which carbonization and liquefaction are the processes with coal tar as the main product. 1,2 Although medium and lowtemperature coal tars have higher contents of aliphatic ...
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Naphthalene has a distinctive, strong odor, which is often described as sweet or tarlike. Its melting point is around 80°C (176°F), and it boils at around 218°C (424°F). Synthesis and Production. Naphthalene is predominantly produced from coal tar, a byproduct of the coal gasification process.
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The Follansbee Tar Plant is involved in coal tar/petroleum (tar and decant oil) refining and naphthalene production. The facility produces pavement sealer bases, refined tars, distillates (coal tar and petroleum), coal tar solvent, various grades of coal tar/petroleum pitch, and refined chemical oil (RCO).
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In a process for obtaining substantially sulfur free pure naphthalene from bituminous coal tar and thionaphthene as a byproduct, a dephenolized thionaphthenecontaining naphthalene fraction from oxidative purification is extracted with concentrated sulfuric acid and acetic acid anhydride in benzene.
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This research presents the first demonstration of substantial microbial degradation and depletion of naphthalene from coal tar, a multicomponent, aromatic, dense nonaqueous phase liquid (NAPL). The rates and extents of microbial degradation of naphthalene from coal tar and from a twocomponent NAPL simpler in composition than coal tar were evaluated in gently mixed, NAPL−water batch systems ...
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The company derives naphthalene from coal tar at production plants in North America, Europe, Australia, and China. NIPPON STEEL SUMITOMO METAL CORPORATION.
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Coal tar, a black, sticky liquid thicker than water, is produced when coal is heated in the absence of air, a process called destructive distillation. Much coal tar is produced by the steel industry as it produces millions of tons of coke each year to fuel the furnaces used in separating iron from its ores.
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100 samples of recycle solvent were obtained by continuous operation (50 days) of 1 ton/day coal liquefaction plant at Kimitu. Naphthalene derivatives in the recycle solvents were anslyzed in ...
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An online condensation system was designed to separate coal tar during cooling process. ... The typical contents of most common specialties in different fractions for coal tar are Light oil, Phenol oil, Naphthalene oil, washing oil, anthracene oil. ... The production yield of total tar was about %, %, % and % for 500, 600, 700 ...
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Naphthalene produced during the distillation of coal tar is crude in nature. Crude Naphthalene is used in the production of tanning agents, household disinfectants etc. It undergoes further fractional distillation to produce some downstream products like sulphonated naphthalene (SNF) and Poly Carboxylate Ether (PCE). PCE is used as a ...
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The organic chemistry industry is based on organic compounds derived from coal, petroleum and gas. Coal tars derived from the carbonisation process are complex mixtures, of which the polycyclic aromatic hydrocarbons (PAH's) are the main component. One of the most important PAH's is naphthalene, which represents between 10 to 12% of the recent years, new applications for industrial ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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